全文获取类型
收费全文 | 70702篇 |
免费 | 4038篇 |
国内免费 | 13064篇 |
专业分类
化学 | 76141篇 |
晶体学 | 903篇 |
力学 | 426篇 |
综合类 | 136篇 |
数学 | 585篇 |
物理学 | 9613篇 |
出版年
2023年 | 2322篇 |
2022年 | 2127篇 |
2021年 | 2394篇 |
2020年 | 3348篇 |
2019年 | 2308篇 |
2018年 | 2678篇 |
2017年 | 2634篇 |
2016年 | 3181篇 |
2015年 | 3352篇 |
2014年 | 4495篇 |
2013年 | 7001篇 |
2012年 | 5771篇 |
2011年 | 5802篇 |
2010年 | 4422篇 |
2009年 | 4630篇 |
2008年 | 3978篇 |
2007年 | 4536篇 |
2006年 | 4122篇 |
2005年 | 2929篇 |
2004年 | 2112篇 |
2003年 | 1912篇 |
2002年 | 1445篇 |
2001年 | 1469篇 |
2000年 | 1012篇 |
1999年 | 1059篇 |
1998年 | 744篇 |
1997年 | 427篇 |
1996年 | 264篇 |
1995年 | 172篇 |
1994年 | 170篇 |
1993年 | 154篇 |
1992年 | 164篇 |
1991年 | 155篇 |
1990年 | 193篇 |
1988年 | 133篇 |
1987年 | 148篇 |
1986年 | 176篇 |
1985年 | 336篇 |
1984年 | 304篇 |
1983年 | 179篇 |
1982年 | 241篇 |
1981年 | 232篇 |
1980年 | 208篇 |
1979年 | 246篇 |
1978年 | 212篇 |
1977年 | 217篇 |
1976年 | 207篇 |
1975年 | 168篇 |
1974年 | 142篇 |
1973年 | 160篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
Mohammad Azam Saud I. Al-Resayes Agata Trzesowska-Kruszynska Rafal Kruszynski S.F. Adil N.K. Lokanath 《Journal of Saudi Chemical Society》2019,23(5):636-641
A new derivative of dioxouranium(VI) salen complex, [UO2(L)(pyridine)], where [L = N,N′-Bis(2-hydroxybenzylidene)-2,2-dimethyl-1,3-propanediamine] is synthesized and characterized by elemental analysis (C, H, N), FT-IR, ESI-MS spectrometry, UV/Vis, fluorescence, 1H and 13C NMR spectroscopy and thermal gravimetric (TG) study. Furthermore, the single crystal X-ray diffraction measurements of the complex were carried out at 100 and 273 K. The crystal structure measurements revealed that the complex has distorted pentagonal bipyramidal geometry with uranium atom located at the centre and bonded to two phenoxy oxygen and two azomethine nitrogen in tetradenate fashion and one nitrogen from pyridine making it seven coordinated. In addition, the photoluminescence property of the complex was also recorded. 相似文献
72.
以1978年改革开放以来人民教育出版社出版的5套高中化学教科书作为研究对象,梳理其物质结构内容的演变,发现近40年来高中化学教科书中物质结构内容选择呈钟摆现象,同时其内容组织的结构化理念日益清晰。此外,为新时期我国高中化学教科书的编写提供了一些建议。 相似文献
73.
Photocatalytic materials are attracting attention as emerging resources for agricultural applications. This timely review assesses the current developments in the use of biocompatible titanium dioxide (TiO2)-based photocatalytic nanomaterials (TiO2-PN) as models to unravel agricultural growth, harvest, and post-harvest problems. Such developments can lead to technological innovations aimed at addressing the pressing global environmental challenges faced by farming. TiO2-PN have been used as antimicrobial, growth-regulating, and fertilizer-like agents. The promising agricultural research applications of TiO2-PN are highlighted along with a discussion of the main challenges that will need to be overcome to fully understand the roles of TiO2-PN in the sustainable and productive exploitation of land and water for agricultural applications under natural conditions. In particular, rhizosphere internalization, translocation, and plant bioaccumulation pathways of photocatalytic materials from environmental exposition are outlined to illustrate the effect of TiO2 on the agricultural cycle. Nanotoxicology and regulations are also discussed to illustrate the importance of biocompatibility and green synthesis of nanomaterials for safe use in real applications. This overview is focused on motivating and intensifying our understanding of on-site agricultural studies. Complementary biological approaches and structural damage observed by biological transmission electron, scanning electron, and optical microscopies should accelerate the practical contribution of TiO2-PN to sustainable agriculture in conjunction with plant factories and plasma nitrogen fixation technology. Loadings below 10 μg/L of TiO2-PN with a size of 40 nm benefit seed germination and root elongation as well as partially suppressing metal root translocation. However, only approximately 5% of current studies were carried out in real agricultural settings. 相似文献
74.
Russian Journal of Organic Chemistry - A rapid and efficient catalytic approach has been proposed for the synthesis of dimethyl 2-[2-(aryl-amino)but-3-en-1-yl]- and... 相似文献
75.
《中国化学快报》2019,30(11):1951-1954
Utilization of intermolecular Friedel-Crafts and intramolecular condensation reaction,novel 1,3-di-(pyridine-2-yl)benzene(N,C,N terdentate) skeleton with electro-withdrawing group in 6' position of pyridyl and a cyclization between 6' position of pyridyl and 6 position of benzyl ring were firstly designed and synthesized.The structures of these novel N,C,N terdentate were confirmed by NMR,MS and X-ray single crystalanalyses.The photophysical properties of these compounds were briefly explored. 相似文献
76.
Excessive consumption of substances such as food colorants, exposure to doses of metal ions, antibiotic residues and pesticides residues above maximum tolerance limit have a detrimental effect on human health. Hence in detecting these harmful substances, the development of sensitive, selective and convenient analytical tools is an essential step. Graphene and graphene like 2D graphitic carbon nitride have shown great promise in the development of electrochemical sensors for determining the levels of these substances in different samples. In this paper, graphene and graphene like 2D graphitic carbon nitride applications on the determination of various food colorants in foods and drinks such as azo dyes (tartrazine, allura red, amaranth, carmine and sunset yellow); metal ions contaminants, antibiotic and pesticide residues in the environment are reviewed. 相似文献
77.
Sheikdawood Parveen Thathan Premkumar Subbiyan Poornima Subbiah Govindarajan 《Journal of Saudi Chemical Society》2019,23(6):691-701
Metal complexes ([ML2], where M = Fe, Co, or Zn; HL = 2-[(6-ethyl-5-oxo-4,5-dihydro-2H-[1,2,4]triazin-3-ylidene)-hydrazono]-butyric acid, C9H13N5O3) of a Schiff base derived from α-ketobutyric acid (α-KBA) and diaminoguanidine (Damgu) were synthesized and characterized using elemental, spectral, and thermal studies. The metal complexes exhibited similar decomposition behavior, with a highly exothermic final decomposition step resulting in the formation of metal oxides. Isomorphism among the complexes was revealed using a powder X-ray diffraction (PXRD) technique. Solid solution precursors ([Zn1/3M2/3(L)2], where M = Fe, Co) were synthesized and characterized using various physico-chemical techniques. A thermal decomposition technique was used to prepare spinel-type zinc cobaltite (ZnCo2O4) and zinc ferrite (ZnFe2O4) nanocrystalline particles with the synthesized single source precursors. Structural studies using PXRD ascertained the predominant crystal phase to be spinel. Transmission electron microscopy (TEM) and high-resolution TEM (HRTEM) showed a mean nanoparticle size of 18 ± 2 nm. Magnetic measurements revealed a weak magnetic behavior in the synthesized spinels. In the aqueous phase, the spinels exhibited catalytic activity, reducing 4-nitrophenol (4-NP) in the presence of NaBH4 at room temperature. Additionally, the study demonstrated that the catalyst can be recovered and reused for five cycles with a more than 85% conversion efficiency. 相似文献
78.
Herein we report a novel visible-light-mediated external reductant-free reductive cross coupling for the construction of C sp~2–C sp~3 bonds. A variety of benzylammonium salts underwent selective coupling with(hetero)aryl nitriles to deliver important diarylmethanes under mild reaction conditions. Importantly, photocatalysts can be omitted for many cases, which might involve the electron donor acceptor(EDA) complex. Mechanistic studies indicated benzylic radicals might be involved as the key intermediates. Moreover, the in situ generated NMe_3 via cleavage of C–N bond in ammonium salts acts as the electron donor,thus avoiding the use of external-reductant. 相似文献
79.
Computational quantum chemical study and biological evaluation of a synthesized novel sulfur heterocyclic thiophene derivative containing 1,2,3-triazole and pyridine moieties namely BTPT [2-(1-benzyl-5-methyl-1H-1,2,3-triazol-4-yl)-6-methoxy-4-(thiophen-2-yl) pyridine] was presented in this study. The crystal structure was determined by SCXRD method. For the title compound BTPT, spectroscopic characterization like 1H NMR, 13C NMR, FTIR, UV–vis were carried out theoretically by computational DFT method and compared with experimental data. Druglikeness parameters of BTPT were found through in silico pharmacological ADMET properties estimation. The molecular docking investigation was performed with human topoisomerase IIα (PDB ID:1ZXM) targeting ATP binding site. In vitro cytotoxicity activity of BTPT/doxorubicin were examined by MTT assay procedure against three human cancer cell lines A549, PC-3, MDAMB-231 with IC50 values of 0.68/0.70, 1.03/0.77 and 0.88/0.98 μM, respectively. Our title compound BTPT reveals notable cytotoxicity against breast cancer cell (MDAMB-231), moderate activity with human lung cancer cell (A-549) and less inhibition with human prostate cancer cell (PC-3) compared to familiar cancer medicine doxorubicin. From the results, BTPT could be observed as a potential candidate for novel anticancer drug development process. 相似文献
80.
Science China Chemistry - 相似文献